Synthesis, molecular structure and DFT study of [(dpp-bian)Ga-M(Et2O)3] (M = Li, Na; dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene).

[摘要]：1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) featuring direct metal-Ga bonds, were prepd. by the redn. of [(dpp-bian)Ga-Ga(dpp-bian)] with two equiv. of Li or Na, resp. The calcd. Ga-Li distance of 2,726 ?for the Li complex is in good agreement with the crystal data.

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