A general and environmentally benign catalytic reduction of nitriles to primary amines.

[摘要]：Primary function: The ruthenium-catalyzed hydrogenation of nitriles to give primary amines has been examd. in detail with 18 different arom. and aliph. nitriles. Superior performance was achieved by using an in situ catalyst, [Ru(cod)methylallyl2] (cod = 1,5-cyclooctadiene) and DPPF.

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