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The first enantioselective addition of diethylzinc to aldehydes in ionic liquids catalyzed by a recyclable ion-tagged diphenylprolinol.

  作者 Lombardo, Marco;Chiarucci, Michel;Trombini, Claudio;  
  选自 期刊  Chemistry-A European Journal;  卷期  2008年14-36;  页码  11288-11291  
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[摘要]Outstanding recyclability: An ion-tagged diphenylprolinol efficiently catalyzes the first asym. addn. of diethylzinc to aldehydes in ionic liqs. Besides good yields and enantiomeric excesses obtained by using only a small excess of alkylating agent, the catalytic system was successfully recycled ten times with no loss of efficiency and catalytic activity.

 
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