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DCC-assisted esterification of a polyoxometalate-functionalized phenol with carboxylic acids (DCC: dicyclohexylcarbodiimide).

  作者 Zhu, Li;Zhu, Yulin;Meng, Xianggao;Hao, Jian;Li, Qiang;Wei, Yongge;Lin, Yuanbin;  
  选自 期刊  Chemistry-A European Journal;  卷期  2008年14-35;  页码  10923-10927  
  关联知识点  
 

[摘要]The phenolic hydroxyl functionalized organoimido polyoxometalate (NBu4)2[Mo6O18NAr] (Ar = p-hydroxy-o-tolyl, POM) undergoes esterification reaction with carboxylic acids in the presence of dicyclohexylcarbodiimide (DCC), to form POM-functionalized esters, providing a convenient and efficient route to prep. POM-based org./inorg. hybrid materials. POM and three esterified products were characterized by x-ray crystallog.

 
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