[摘要]:The phenolic hydroxyl functionalized organoimido polyoxometalate (NBu4)2[Mo6O18NAr] (Ar = p-hydroxy-o-tolyl, POM) undergoes esterification reaction with carboxylic acids in the presence of dicyclohexylcarbodiimide (DCC), to form POM-functionalized esters, providing a convenient and efficient route to prep. POM-based org./inorg. hybrid materials. POM and three esterified products were characterized by x-ray crystallog.