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Multinuclear alkylaluminum macrocyclic Schiff base complexes: influence of procatalyst structure on the ring opening polymerisation of e-caprolactone.

  作者 Arbaoui, Abdessamad;Redshaw, Carl;Hughes, David L.;  
  选自 期刊  Chemical Communications;  卷期  2008年-39;  页码  4717-4719  
  关联知识点  
 

[摘要]Two remote dialkyl-aluminum centers supported by a macrocyclic Schiff base ligand exhibited beneficial cooperative effects, while aluminoxane-type bonding proved to be detrimental to activity for the ring opening polymn. of e-caprolactone.

 
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