Diaryl ether synthesis in supercritical carbon dioxide in batch and continuous flow modes.
作者
Lee, Jin-Kyun;Fuchter, Matthew J.;Williamson, Rachel M.;Leeke, Gary A.;Bush, Edward J.;McConvey, Ian F.;Saubern, Simon;Ryan, John H.;Holmes, Andrew B.;
[摘要]：A high yielding, batch mode synthesis of diaryl ethers and sulfides by an SNAr fluoride-mediated process in scCO2 has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.
