Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O52(m9-SO3)]7-.
作者
Miras, Haralampos N.;Stone, Daniel J.;McInnes, Eric J. L.;Raptis, Raphael G.;Baran, Peter;Chilas, George I.;Sigalas, Michael P.;Kabanos, Themistoklis A.;Cronin, Leroy;
[摘要]：A polyoxomolybdenum/V-sulfite {M18} cluster-based compd., [MoVI11VV5VIV2O52(m9-SO3)]7-, is reported that exhibits a unique structural motif, arising from the incorporation of five VV and two VIV ions into a {M18} cluster framework templated by SO32-; this cluster compn. was 1st identified using cryospray mass spectrometry.
