Competition between planar and central chiral control elements in nucleophilic addition to ferrocenyl imine derivatives.

[摘要]：Planar chirality assocd. with the ferrocene in ferrocenyl oximes and hydrazones bearing chiral auxiliaries effectively competes with or overrides the normally excellent stereocontrol afforded by the auxiliary in detg. the diastereoselectivity of addn. to the C:N bond.

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