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Rotational spectrum and equilibrium structure of silanethione, H2Si:S.

  作者 Thorwirth, Sven;Gauss, Juergen;McCarthy, Michael C.;Shindo, Francois;Thaddeus, Patrick;  
  选自 期刊  Chemical Communications;  卷期  2008年-42;  页码  5292-5294  
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[摘要]Unsubstituted silanethione, H2Si:S, has been characterized exptl. for the first time by means of rotational spectroscopy; the equil. structure of this fundamental mol. has been evaluated through a combination of exptl. data from a total of ten isotopologues and results of high-level coupled-cluster calcns.

 
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