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N,N'-Disubstituted Methylenediimidazolium Salts: A Versatile Guest for Various Macrocycles.

  作者 Noujeim, Nadim;Leclercq, Loic;Schmitzer, Andreea R.;  
  选自 期刊  Journal of Organic Chemistry;  卷期  2008年73-10;  页码  3784-3790  
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[摘要]N,N'-Disubstituted methylenediimidazolium salts allow the formation of flexible inclusion complexes with b-cyclodextrin, cucurbit[7]uril, tetrapropoxycalix[4]arene, and dibenzo-24-crown-8 ether. Due to the salt nature of the imidazolium guest, the counterion largely dets. its soly. in a given solvent. Moreover, by the judicious choice of the imidazolium substituents, inclusion complexes of guest salts were obtained with a variety of macrocyclic hosts, and the binding parameters of the inclusion were detd. for each complex.

 
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