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An Expedient Synthesis of Mellitic Triimides.

  作者 Rose, Kathryn G.;Jaber, Dina A.;Gondo, Chenaimwoyo A.;Hamilton, Darren G.;  
  选自 期刊  Journal of Organic Chemistry;  卷期  2008年73-10;  页码  3950-3953  
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[摘要]Heating of the solid ammonium salts obtained from treatment of mellitic acid with 3 equiv of a primary amine yields trisubstituted mellitic triimides, e.g., I, via dehydration and imide ring closure. This surprisingly simple synthetic approach is amenable to incorporation of alkyl, aryl, and amino acid ester substituents, thereby opening broad access to a family of C3-sym. org. electron acceptors.

 
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