Axial Coordination of NHC Ligands on Dirhodium(II) Complexes: Generation of a New Family of Catalysts.
作者
Trindade, Alexandre F.;Gois, Pedro M. P.;Veiros, Luis F.;Andre, Vavecnia;Duarte, M. Teresa;Afonso, Carlos A. M.;Caddick, Stephen;Cloke, F. Geoffrey N.;
[摘要]：An efficient new methodol. for the arylation of aldehydes is disclosed ligands. Complexes of Rh2(OAc)4 with one and two NHCs attached on the axial positions were successfully isolated, fully characterized, and used as catalysts in the reaction. A satd. monocomplex is the most active catalyst and was particularly efficient in the arylation of alkyl aldehydes. DFT calcns. support participation of complexes with one axial NHC in the reaction as the catalysts active species and indicate that hydrogen bonds involving dirhodium unit, reactants, and solvent (alc.) play an important role on the reaction mechanism.
