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Understanding the Behavior of N-Tosyl and N-2-Pyridylsulfonyl Imines in CuII-Catalyzed Aza-Friedel-Crafts Reactions.

  作者 Alonso, Ines;Esquivias, Jorge;Gomez-Arrayas, Ramon;Carretero, Juan C.;  
  选自 期刊  Journal of Organic Chemistry;  卷期  2008年73-16;  页码  6401-6404  
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[摘要]The different behavior of N-tosyl imines and N-(2-pyridyl)sulfonyl imines in CuII-catalyzed AFCR is described. DFT theor. calcns. on the mode of coordination of the copper atom to both types of substrates allow understanding this different reactivity.

 
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