Copper(I)-Promoted Synthesis of Chloromethyl Ketones from Trichloromethyl Carbinols.

[摘要]：Reaction of several trichloromethyl carbinols with 2 equiv of CuCl/bpy in refluxing DCE for 3 h afforded chloromethyl ketones in excellent yield by 1,2-H shift in the copper-chlorocarbenoid intermediate.

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