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Gold(I)-Catalyzed Intramolecular Rearrangement of Vinylidenecyclopropanes.

  作者 Shi, Min;Wu, Lei;Lu, Jian-Mei;  
  选自 期刊  Journal of Organic Chemistry;  卷期  2008年73-21;  页码  8344-8347  
  关联知识点  
 

[摘要]Vinylidenecyclopropanes 1 can undergo intramol. rearrangement to give the corresponding functionalized 1,2-dihydronaphthalenes in the presence of gold catalyst under mild conditions. A plausible rearrangement mechanism has been proposed on the basis of control expts.

 
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