A Nonsymmetric Pincer-Catalyzed Suzuki-Miyaura Arylation of Benzyl Halides and Other Nonactivated Unusual Coupling Partners.

[摘要]：The catalytic activity of a PCN-type palladium pincer complex I is evaluated in the construction of C(sp2)-C(sp2) and C(sp2)-C(sp3) bonds by Suzuki-Miyaura cross-couplings employing nontypical substrates such as benzyl halides, a-haloenones, or alkylboronic acids as coupling partners. Most of the reported reactions are achieved in aq. media, with all of the advantages implied.

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