Asymmetric Epoxidation of 1,1-Disubstituted Terminal Olefins by Chiral Dioxirane via a Planar-like Transition State.

[摘要]：Various 1,1-disubstituted terminal olefins underwent asym. epoxidn. using chiral ketone catalysts that were prepd. from glucose. Up to 88% ee was achieved with a lactam ketone I, and a planar transition state is likely to be a major reaction pathway.

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