Molybdenum(VI) dichloride dioxide catalyzed synthesis of b-keto esters by C-H insertion of ethyl diazoacetate into aldehydes.

[摘要]：Synthesis of b-keto esters by condensing various aldehydes with Et diazoacetate was achieved by using molybdenum(VI) dichloride dioxide. Arom., aliph., and heterocyclic aldehydes were successfully condensed with Et diazoacetate to obtain corresponding b-keto esters in high yields at room temp.

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