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Synthesis of a new type of D-mannosamine glycosyl donor and acceptor and their use for the preparation of oligosaccharides consisting of D-mannosamine units linked by a(1?)-glycosidic bonds.

  作者 Tursky, Matyas;Vesely, Jan;Tislerova, Iva;Trnka, Tomas;Ledvina, Miroslav;  
  选自 期刊  Synthesis;  卷期  2008年-16;  页码  2610-2616  
  关联知识点  
 

[摘要]Herein, we present the synthesis of three new 2-azido-2-deoxy-D-mannopyranose building blocks that are useful in the prepn. of oligosaccharides consisting of a(1?)-linked 2-azido-2-deoxy-D-mannopyranose units. The successful utilization of these intermediates in the stepwise synthesis of the corresponding trisaccharide is also described in detail.

 
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