Mechanistic studies on the roles of cosolvents and additives in samarium(II)-based reductions.

[摘要]：A review. This account describes work, performed by the author's research group during the past decade, designed to understand the mechanistic roles of cosolvents and additives in redns. involving SmI2. Emphasis is placed on studies designed to elucidate the roles of the cosolvent hexamethylphosphoramide (HMPA) and proton donors (water, alcs., and glycols) in the mechanisms of important bond-forming reactions and redns. initiated by SmI2.

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