Expedient Mukaiyama-type Mannich reaction catalyzed by lithium chloride.

[摘要]：The Mannich reaction of methylsilyl enol ether with aryl aldimine proceeded in the presence of a catalytic amt. of LiCl in DMF at room temp. The reaction was mild enough to apply to aldimines having the AcO, Me3CMe2SiO, or MeS group. Microwave irradn. accelerated the reaction substantially to reduce reaction time.

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