[摘要]：Asym. p-allylic substitution of meso-1,4-diacetoxycyclopentene and -cyclohexene with various nucleophiles was performed with an resin-supported chiral imidazoindolephosphine-palladium complex in water as a single reaction medium under heterogeneous conditions to give the corresponding 4-substituted 1-acetoxy cycloalkenes with ?9% ee.
