Synthesis of 3-alkyl-1H-quinolin-2-ones via palladium-catalyzed intramolecular cyclization of benzyl halides and a,b-unsaturated amides.
[摘要]:An efficient synthesis of 3-alkyl-1H-quinolin-2-ones was achieved in high yield (up to 91%) via Pd2(dba)3-catalyzed intramol. cyclization of benzyl halides and electron-deficient olefins, followed by treatment with DBU.
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