Synthetic studies directed toward kaitocephalin: a highly stereocontrolled route to the right-hand pyrrolidine core.

[摘要]：A highly stereocontrolled method for the construction of the right-hand segment of kaitocephalin, an antagonist of AMPA/KA and NMDA glutamate receptors, was developed employing palladium-catalyzed cyclization of an oxiranylacrylate at the quaternary center as the key step.

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