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Beckmann rearrangement of oximes catalyzed by cyanuric chloride in ionic liquids.

  作者 Betti, Cecilia;Landini, Dario;Maia, Angelamaria;Pasi, Maurizio;  
  选自 期刊  SYNLETT;  卷期  2008年-6;  页码  908-910  
  关联知识点  
 

[摘要]The Beckmann rearrangement of a variety of ketoximes was carried out in imidazolium-based ionic liqs. in the presence of catalytic amts. of 2,4,6-trichloro[1,3,5]triazine. This mild and green procedure is highly regioselective affording the corresponding N-substituted amides in very good to quant. yields. The ionic liqs. were easily recovered and recycled several times.

 
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