A Formal Synthesis of the Auriside Aglycon.

[摘要]：A highly convergent formal synthesis of the auriside aglycon was achieved. An indene-based thiazolidinethione chiral auxiliary (I) was fragments via acetate aldol reactions. A Meinwald reaction was utilized to install the stereocenter at C2, and a conjugated addn. to an ynone was used to construct the C9-C11 enone.

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