[摘要]:Photochemistry, and Photographic and Other Reprographic The title trifluoroacetylaminophthalimide deriv. produced a violet fluorescence (lFLmax 392 nm) in MeCN, and it displayed a green emission (lFLmax 506 nm) after irradn. at 254 nm in the presence of iodide ions. The corresponding amidate ion of the trifluoroacetamide was identified as the green fluorescence emitter. The deprotonation reaction may be caused by proton-abstracting solvated electrons generated by a photochem. charge-transfer-to-solvent process from I- to MeCN.