Cu(I)-Catalyzed asymmetric diamination of conjugated dienes.

[摘要]：A Cu(I)-catalyzed asym. diamination for a variety of conjugated dienes and a triene with encouraging ee's has been effectively achieved using (R)-DTBM-SEGPHOS (I) as a chiral ligand and di-tert-butyldiaziridinone as the nitrogen source.

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