A Bench-Stable Pd Catalyst for the Hydroarylation of Fullerene with Boronic Acids.

[摘要]：A Pd(II) catalyst for the hydroarylation of fullerene with boronic acids is presented. Treatment of C60 with an arylboronic acid ArB(OH)2 (Ar = Ph, 4-MeC6H4, 4-ClC6H4, 4-AcC6H4, 3-thienyl, etc.) in the presence of a catalytic amt. of Pd(2-PyCH=NPh)(OCOC6F5)2 in H2O/1,2-Cl2C6H4 at room temp. furnishes the hydroarylation product (Ar-C60-H) in good yield with high selectivity. This complex possesses high catalytic activity paired with bench stability in the solid state.

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