Nickel-Catalyzed Borylative Ring-Opening Reaction of Vinylcyclopropanes with Bis(pinacolato)diboron Yielding Allylic Boronates.

[摘要]：Vinylcyclopropanes bearing one or two electron-withdrawing groups on the cyclopropane ring undergo nickel-catalyzed borylative ring opening with bis(pinacolato)diboron to yield allylic boronates. The reaction proceeded with high E selectivity.

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