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[摘要]:A review. Organocatalytic asym. synthesis has been extensively studied and several important procedures for prepg. optically active org. compds. have been developed. This review addresses the most significant advances in asym. synthesis using proline and related chiral organocatalysts, mainly from the viewpoint of synthetic applications. a-oxidn., (4) a-amination, (5) a-sulfenylation / selenenylation, (6) a-halogenation, (7) cycloaddn. reactions, and (8) misc. reactions such as C-C bond formation, epoxidn. / oxidn., and redn. |
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