【文章名】Synthesis of nitrogen heterocycles by intramolecular cyclization of alkenyl N-acylaminophthalimides using phenyliodine(III) bis(trifluoroacetate) (PIFA).
Synthesis of nitrogen heterocycles by intramolecular cyclization of alkenyl N-acylaminophthalimides using phenyliodine(III) bis(trifluoroacetate) (PIFA).
[摘要]:PIFA-mediated intramol. cyclization of alkenyl N-acylaminophthalimides leads to the formation of a new C-N bond via an N-acyl-N-phthalimidonitrenium ion intermediate. The reaction pathway also results in the introduction of an oxygen function into the mol. giving added versatility to this single step procedure.