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Reaction of dithiolactones with benzyne: a novel synthesis of benzo-1,3-dithioles.

  作者 Okuma, Kentaro;Nojima, Akiko;Yokomori, Yoshinobu;  
  选自 期刊  Heterocycles;  卷期  2008年75-6;  页码  1417-1424  
  关联知识点  
 

[摘要]Compounds (More Than One Hetero Atom)) Section The reaction of benzyne with several kinds of dithiolactones, such as b-dithiolactone, benzothiophene-1-thione, 1,2-dithiolane-3-thione, and 3,3,5,5-tetramethyl-4-thioxothiolane-2-thione, afforded benzo-1,3-dithioles, e.g., I, in moderate to good yields, whereas the reaction of benzyne with g-thionolactone gave g-lactone and di-Ph disulfide.

 
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