[摘要]:Chiral ligands contg. an oxazoline substituent and a sulfur functionality at the furan ring were synthesized and examd. for enantioselective Pd-catalyzed allylic substitution reaction. The enantioselectivity obsd. was dependent on the nature of the S center and oxazoline group, giving ?1% ee with a chiral 3-sulfinylfur-2-yl ligand.