Synthesis of highly oxygenated biphenyl derivative in an optically active form through palladium-mediated intramolecular biaryl coupling reaction.

[摘要]：Optically active 6,6'-bis(hydroxymethyl)-2,2',3,3',4,4'-hexamethoxybiphenyl was prepd. via the Pd-mediated biaryl coupling reaction of a Ph benzoate deriv. and the following enantioselective lactone opening reaction.

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