Palladium(II)-catalyzed cyclization via N-alkylation of an allyl alcohol with an urethane and its application to the syntheses of natural products.

[摘要]：A review. Stereoselective amino-palladation of alkenylamines is one of the most important approaches for the stereoselective construction of N-hetero-alicycles, which form the skeletons of several biol. active natural products and related compds. We reviewed our work with the utility of palladium(II)-catalyzed cyclization via N-alkylation of an allyl alc. with a urethane. The syntheses of natural products by using Pd(II)-catalyzed cyclization were also reviewed.

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