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Reaction of epoxyketones with hydrogen peroxide - ethane-1,1-dihydroperoxide as a surprisingly stable product.

  作者 Hamann, Hans-Juergen;Bunge, Alexander;Liebscher, Juergen;  
  选自 期刊  Chemistry-A European Journal;  卷期  2008年14-23;  页码  6849-6851  
  关联知识点  
 

[摘要]formed together with several other products when cyclic epoxyketones were treated with H2O2 under acid catalysis following a complex novel reaction pathway. Several C-C bond cleavages under Baeyer-Villiger oxidn. and hydro-peroxide rearrangements occur.

 
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