A novel selective aza-Morita-Baylis-Hillman (aza-MBH) domino reaction and aza-MBH reaction of N-sulfonated imines with acrolein catalyzed by a bifunctional phosphine organocatalyst.

[摘要]：The first aza-MBH/Michael/aldol/dehydrate domino reaction has been described. In the presence of a bifunctional phosphine organocatalyst the N-sulfonated imines and acrolein gave the tetrahydropyridine derivs., e.g., I, and aza-MBH products, e.g., II, selectively in good to excellent yields.

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