【文章名】C-H insertion processes on stabilized indolyl and ortho-aminophenyl Fischer carbene complexes: synthesis of azepino[3,2,1-hi]indole, benzazepine and indole derivatives.
C-H insertion processes on stabilized indolyl and ortho-aminophenyl Fischer carbene complexes: synthesis of azepino[3,2,1-hi]indole, benzazepine and indole derivatives.
[摘要]：Compounds (More Than One Hetero Atom)) Section A new sequential [n + 2] cycloaddn./C-H insertion reaction of indolylalkynyl and ortho-aminophenylalkynyl Fischer carbene complexes that leads to azepino[3,2,1-hi]indole, benzazepine, and indole derivs. is described. As an extension of this chem. behavior, 1,2-disubstituted indoles can be obtained from methoxy ortho-aminophenyl Fischer carbene complexes.
