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[摘要]：Photographic and Other Reprographic Processes) Section The authors have prepd. two complementary series of SubPc-C60 (SubPc = subphthalocyanine) electron/energy donor-acceptor systems, in which the two constituents are linked through ortho-, meta-, or para-substituted phenoxy spacers. In one of the series (1a) the SubPc units bear iodine atoms, while in the other series (1b) diphenylamino groups are linked to the SubPc macrocycles. The iodine atoms and diphenylamino groups both influence the resulting oxidn. potentials of the electron-donating SubPc. They also modulate the outcome of excited state interactions, namely, energy and/or charge transfer. In addn., the authors have studied the impact that the substitution pattern in the phenoxy spacer exerts onto intramol. processes in the ground and excited states. Although some of these processes are governed by the spatial sepn. between both components, the different electronic coupling through ortho-, meta-, or para-connections also plays decisive roles in some cases. |
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