Highly enantioselective organocatalytic formation of a quaternary carbon center via chiral Bronsted acid catalyzed self-coupling of enamides.

[摘要]：Derivatives, and Condensed Benzenoid Compounds) Section The enantioselective BINOL-phosphate catalyzed formation of a quaternary carbon center, bearing a N-atom has been achieved through the self-coupling reaction of enamides. The corresponding products have been isolated in up to >99% ee and their application for the synthesis of versatile synthetic building blocks, b-aminoketones, has been demonstrated.

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