Total Synthesis of (-)-Kendomycin.

[摘要]：An enantioselective synthesis of (-)-kendomycin (I) is described and is based on the application of the organosilane-based [4 + 2]-annulation strategy for the assembly of the C1a-C10 fragment. An underutilized samarium(II) iodide-assisted cyclization (intramol. Barbier-type reaction) is employed to afford the protected macrocycle.

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