[摘要]:N-Arylation of N-containing heterocycles, such as pyrazoles, imidazoles, and benzimidazoles with aryl-, heteroaryl- and vinylboronic acids was efficiently carried out by copper fluorapatite (CuFAP) catalyst in MeOH at room temperature under base-free conditions. The N-arylated heterocylces were isolated in good-to-excellent yields.