Enantioselective Palladium-Catalyzed Allylic Substitution of Sodium Benzotriazolide

[摘要]：Chiral allylic benzotriazole-containing regioisomers 4 and 5 were synthesized by enantioselective palladium-catalyzed allylation of sodium benzotriazolide with a range of allylic carbonates in 50-89% yields, regioselectivities of 2.2:1 to 1:3.4, and ee values of up to 95%.

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