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Synthesis of Aryl Stannanes from Silyl Triflates via Aryne Intermediates

  作者 LAKSHMI B VASANTHA; WEFELSCHEID ULRIKE K; KAZMAIER ULI  
  选自 期刊  SYNLETT;  卷期  2011年-3;  页码  345-348  
  关联知识点  
 

[摘要]Aryl stannanes are easily accessible from o-silylated aryl triflates in the presence of KF and Bu3SnH. The corresponding arynes are formed in situ, and undergo clean hydrostannation to give a mixture of the regioisomeric aryl stannanes. The whole reaction sequence can also be carried out as a one-pot reaction under microwave irradiation.

 
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