Stereoselective Synthesis of (E)-alpha-Fluorovinylphosphonates from alpha,alpha-Difluorophosphonates

[摘要]：alpha,alpha-Difluorophosphonates, which are readily available from alkyl halides and diethyl difluoromethylphosphonate, undergo elimination of hydrogen fluoride using alkali metal alkoxides to provide alpha-fluorovinylphosphonates in high yields and E/Z selectivities.

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