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[摘要]:A new controllable and regioselective allylic alkylation and amination reaction has been developed for the highly selective construction of compounds containing alpha-alkylidene-beta-amino acid and alpha-methylene-gamma-butyrolactam moieties. Furthermore, on the basis of this controllable strategy, multicomponent tandem reactions have also been accomplished. The subsequent transformations of the densely functionalized products have readily afforded a range of useful building blocks, which have potential utility in organic synthesis. |
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