Gold-catalysed cascade rearrangements of ynamide propargyl esters

[摘要]：The Au(I)-catalysed rearrangement of propargylic esters formed from an ynamide has been studied. The reaction is facile, and when conducted in the presence of a reactive indole nucleophile, leads to a cascade process whereby gamma-indolyl alpha-acyloxyenamides are formed in good yield and excellent E-stereoselectivity.

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