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Stereoselective 6 pi-Electron Electrocyclic Ring Closures of 2-Halo-Amidotrienes via a Remote 1,6-Asymmetric Induction

  作者 HAYASHI RYUJI; WALTON MARY C; HSUNG RICHARD P; SCHWAB JOHN H; YU XUELIANG  
  选自 期刊  Organic Letters;  卷期  2010年12-24;  页码  5768-5771  
  关联知识点  
 

[摘要]A diastereoselective 6 pi-electrocyclic ring closure employing halogen-substituted 3-amidotrienes via a 1,6-remote asymmetric induction is described. This new asymmetric manifold for pericyclic ring closure further underscores the significance of the allenamide chemistry.

 
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