Bis(imino)pyridine Iron Complexes for Aldehyde and Ketone Hydrosilylation.

[摘要]：Derivatives, and Condensed Benzenoid Compounds) Section Bis(imino)pyridine iron dinitrogen and dialkyl complexes are well-defined precatalysts for the chemo- and regioselective redn. of aldehydes and ketones. Efficient carbonyl hydrosilylation is obsd. at low (0.1-1.0 mol %) catalyst loadings and with 2 equiv of either PhSiH3 or Ph2SiH2, representing one of the most active iron-catalyzed carbonyl redns. reported to date.

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